Dimethyl (N, N, N', N'-tetramethylethanediamine) palladium (II) and dimethyl [1, 2-bis (dimethylphosphino) ethane] palladium (II): syntheses, x-ray crystal structures …

W De Graaf, J Boersma, WJJ Smeets, AL Spek… - …, 1989 - ACS Publications
I;-20 C for X= Br). When these solutions are warmed up (>-20 C for 4a;> 0 C for 4b), ethane
is eliminated with the formation of PdXMe (tmeda)(3a, b). PdMe2 (tmeda) reacts with MeOTf …

New neutral and ionic methyl and chloro palladium and platinum complexes containing hemilabile phosphorus-nitrogen ligands. Study of the insertion of carbon …

GPCM Dekker, A Buijs, CJ Elsevier, K Vrieze… - …, 1992 - ACS Publications
PAN, PC3N) ligand temporarily functions as a monodentate phosphorus-bonded ligand, ie [trans
P, cis CH3 (Pt-CO)],[cis P, trans CH3 (Pt-CO)], and [cis P, cis CH3 (Pt-CO)], which for …

Alkene and Carbon Monoxide Insertion Reactions of Nitrogen-Coordinated Monoorganopalladium (II) Complexes: The Stepwise Construction of Alternating …

BA Markies, D Kruis, MHP Rietveld… - Journal of the …, 1995 - ACS Publications
The stepwise synthesis of a palladium (II) bound alternating oligomer of CO and strained
alkenes is described together with the factors that allow full control of each successive step. …

Synthesis of cyclic bifunctional organomagnesium compounds. X-ray crystal structures of tetrameric organomagnesium clusters

MAGM Tinga, G Schat, OS Akkerman… - Journal of the …, 1993 - ACS Publications
Three cyclic bifunctional organomagnesium compounds were prepared by three different
routes. Reaction of 1, 8-dibromo-or 1, 8-diiodonaphthalene with metallic magnesium gave the …

Cyclopalladation of 2-[(Dimethylamino) methyl]-Substituted Naphthalenes: 1-vs 3-Palladation. Crystal Structures of [Hydrotris (pyrazolyl) borato][2-[(dimethylamino) …

JM Valk, F Maassarani, P van der Sluis, AL Spek… - …, 1994 - ACS Publications
The oxidation of substituted naphthalenes is an im-portant process, because some of the
oxidation products are of interest for pharmaceutical applications. For example, 2-methyl-l, 4-…

Influence of the amino substituents of potentially bis ortho chelating aryl ligands (2, 6-{R1R2NCH2} 2C6H3)-on the synthesis and properties of their organonickel (II) …

JAM Van Beek, G Van Koten, MJ Ramp… - Inorganic …, 1991 - ACS Publications
(R'R2NCN')], by reaction with 0.5 equiv of Br2. The molecular structures of three complexes
havebeen determined by X-ray crystallographic methods.[NiBr (C6H3| CH2N (i-Pr) Me| 2-2, 6…

Synthesis, characterization, and reactions of rhodium (I) and iridium (I) bis (iminophosphoranyl) methanide complexes in which the ligand acts as a. sigma.-N,. sigma …

P Imhoff, R van Asselt, JM Ernsting, K Vrieze… - …, 1993 - ACS Publications
Synthesis, characterization, and reactions of rhodium(I) and iridium(I) bis(iminophosphoranyl)methanide
complexes in which the l Page 1 Organometallics 1993, 12, 1523-1536 1523 Synthesis …

X-ray structures and redox properties of copper (II) bis (pyrazole) complexes

CF Martens, APHJ Schenning, MC Feiters… - Inorganic …, 1995 - ACS Publications
The copper complexes of bis [2-(3, 5-dimethyl-l-pyrazolyl) ethyl] amine (1) and its benzylated
derivative (2) have been studied as single crystals by X-ray crystallography and as …

Organozinc complexes with monoanionic chelating phenolates or 2-pyridylmethanolates. Molecular structure of [Zn (CH2SiMe3){OCH2 (2-Py)}] 4

PA van der Schaaf, E Wissing, J Boersma… - …, 1993 - ACS Publications
The coordination chemistry of organozinc alkoxides and aryloxides is very diverse. 1-8
Although normally tetrameric association is observed with a distorted cubic Zn404 core as a …

Reaction of (C5H5) 2NbH3 with (C5H5) 2Zn-structure of (C5H5) 2NbH2ZnC5H5

PHM Budzelaar, KH Den Haan, J Boersma… - …, 1984 - ACS Publications
Three compounds containing niobium-zinc bondshave been obtained from the reaction of
Cp2NbH3 with Cp2Zn. When the reaction was carried out in benzene, the use of an excess of …