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Manoharan Mariappan
Manoharan Mariappan
North Florida College
Verified email at nfc.edu
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Cited by
Year
Dissected nucleus-independent chemical shift analysis of π-aromaticity and antiaromaticity
PR Schleyer, M Manoharan, ZX Wang, B Kiran, H Jiao, R Puchta, ...
Organic Letters 3 (16), 2465-2468, 2001
9512001
Electronic basis of improper hydrogen bonding: a subtle balance of hyperconjugation and rehybridization
IV Alabugin, M Manoharan, S Peabody, F Weinhold
Journal of the American Chemical Society 125 (19), 5973-5987, 2003
8292003
The acenes: is there a relationship between aromatic stabilization and reactivity?
PR Schleyer, M Manoharan, H Jiao, F Stahl
Organic letters 3 (23), 3643-3646, 2001
3722001
Rules for anionic and radical ring closure of alkynes
IV Alabugin, K Gilmore, M Manoharan
Journal of the American chemical society 133 (32), 12608-12623, 2011
1802011
Homoanomeric effects in six-membered heterocycles
IV Alabugin, M Manoharan, TA Zeidan
Journal of the American Chemical Society 125 (46), 14014-14031, 2003
1732003
Control of kinetics and thermodynamics of [1, 5]-shifts by aromaticity: a view through the prism of Marcus theory
IV Alabugin, M Manoharan, B Breiner, FD Lewis
Journal of the American Chemical Society 125 (31), 9329-9342, 2003
1412003
Dissected nucleus-independent chemical shift analysis of pi-aromaticity and antiaromaticity.
P von Ragué Schleyer, M Manoharan, ZX Wang, B Kiran, H Jiao, ...
Organic letters 3 (16), 2465-2468, 2001
1302001
5-Exo-dig radical cyclization of enediynes: the first synthesis of tin-substituted benzofulvenes
SV Kovalenko, S Peabody, M Manoharan, RJ Clark, IV Alabugin
Organic Letters 6 (14), 2457-2460, 2004
1262004
Tuning rate of the bergman cyclization of benzannelated enediynes with ortho substituents
IV Alabugin, M Manoharan, SV Kovalenko
Organic Letters 4 (7), 1119-1122, 2002
1212002
σ-Antiaromaticity in cyclobutane, cubane, and other molecules with saturated four-membered rings
D Moran, M Manoharan, T Heine, PVR Schleyer
Organic Letters 5 (1), 23-26, 2003
1202003
Reactant destabilization in the Bergman cyclization and rational design of light-and pH-activated enediynes
IV Alabugin, M Manoharan
The Journal of Physical Chemistry A 107 (18), 3363-3371, 2003
1092003
Radical-Anionic Cyclizations of Enediynes:  Remarkable Effects of Benzannelation and Remote Substituents on Cyclorearomatization Reactions
IV Alabugin, M Manoharan
Journal of the American Chemical Society 125 (15), 4495-4509, 2003
1082003
Hybridization trends for main group elements and expanding the Bent’s rule beyond carbon: More than electronegativity
IV Alabugin, S Bresch, M Manoharan
The Journal of Physical Chemistry A 118 (20), 3663-3677, 2014
1072014
Radical Cascade Transformations of Tris(o-aryleneethynylenes) into Substituted Benzo[a]indeno[2,1-c]fluorenes
IV Alabugin, K Gilmore, S Patil, M Manoharan, SV Kovalenko, RJ Clark, ...
Journal of the American Chemical Society 130 (34), 11535-11545, 2008
1052008
Triplet acetylenes as synthetic equivalents of 1, 2-bicarbenes: Phantom n, π* state controls reactivity in triplet photocycloaddition
TA Zeidan, SV Kovalenko, M Manoharan, RJ Clark, I Ghiviriga, ...
Journal of the American Chemical Society 127 (12), 4270-4285, 2005
1032005
Thermodynamic and strain effects in the competition between 5-exo-dig and 6-endo-dig cyclizations of vinyl and aryl radicals
IV Alabugin, M Manoharan
Journal of the American Chemical Society 127 (36), 12583-12594, 2005
972005
Effect of double-hyperconjugation on the apparent donor ability of σ-bonds: Insights from the relative stability of δ-substituted cyclohexyl cations
IV Alabugin, M Manoharan
The Journal of Organic Chemistry 69 (26), 9011-9024, 2004
952004
Aromatic transition states in nonpericyclic reactions: anionic 5-endo cyclizations are aborted sigmatropic shifts
K Gilmore, M Manoharan, JIC Wu, PR Schleyer, IV Alabugin
Journal of the American Chemical Society 134 (25), 10584-10594, 2012
872012
Ortho effect in the Bergman cyclization: comparison of experimental approaches and dissection of cycloaromatization kinetics
TA Zeidan, SV Kovalenko, M Manoharan, IV Alabugin
The Journal of Organic Chemistry 71 (3), 962-975, 2006
872006
Blue-Shifted and Red-Shifted Hydrogen Bonds in Hypervalent Rare-Gas FRg− H⊙⊙⊙ Y Sandwiches
IV Alabugin, M Manoharan, FA Weinhold
The Journal of Physical Chemistry A 108 (21), 4720-4730, 2004
862004
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