Paving the way for lignin valorisation: recent advances in bioengineering, biorefining and catalysis

R Rinaldi, R Jastrzebski, MT Clough… - Angewandte Chemie …, 2016 - Wiley Online Library
Lignin is an abundant biopolymer with a high carbon content and high aromaticity. Despite
its potential as a raw material for the fuel and chemical industries, lignin remains the most …

The catalytic valorization of lignin for the production of renewable chemicals

J Zakzeski, PCA Bruijnincx, AL Jongerius… - Chemical …, 2010 - ACS Publications
Biomass is an important feedstock for the renewable production of fuels, chemicals, and
energy. As of 2005, over 3% of the total energy consumption in the United States was supplied …

New trends for metal complexes with anticancer activity

PCA Bruijnincx, PJ Sadler - Current opinion in chemical biology, 2008 - Elsevier
Medicinal inorganic chemistry can exploit the unique properties of metal ions for the design
of new drugs. This has, for instance, led to the clinical application of chemotherapeutic …

Formation, molecular structure, and morphology of humins in biomass conversion: influence of feedstock and processing conditions

I Van Zandvoort, Y Wang, CB Rasrendra… - …, 2013 - Wiley Online Library
Neither the routes through which humin byproducts are formed, nor their molecular structure
have yet been unequivocally established. A better understanding of the formation and …

[HTML][HTML] New insights into the structure and composition of technical lignins: a comparative characterisation study

S Constant, HLJ Wienk, AE Frissen, P De Peinder… - Green …, 2016 - pubs.rsc.org
Detailed insight into the structure and composition of industrial (technical) lignins is needed
to devise efficient thermal, bio- or chemocatalytic valorisation strategies. Six such technical …

Mononuclear non-heme iron enzymes with the 2-His-1-carboxylate facial triad: recent developments in enzymology and modeling studies

PCA Bruijnincx, G van Koten… - Chemical Society …, 2008 - pubs.rsc.org
Iron-containing enzymes are one of Nature’s main means of effecting key biological transformations.
The mononuclear non-heme iron oxygenases and oxidases have received the most …

Chemocatalytic conversion of ethanol into butadiene and other bulk chemicals

C Angelici, BM Weckhuysen, PCA Bruijnincx - ChemSusChem, 2013 - Wiley Online Library
The development of new and improved processes for the synthesis of bio‐based chemicals
is one of the scientific challenges of our time. These new discoveries are not only important …

Catalytic lignin valorization process for the production of aromatic chemicals and hydrogen

J Zakzeski, AL Jongerius, PCA Bruijnincx… - …, 2012 - Wiley Online Library
With dwindling reserves of fossil feedstock as a resource for chemicals production, the
fraction of chemicals and energy supplied by alternative, renewable resources, such as lignin, …

Shale gas revolution: an opportunity for the production of biobased chemicals?

PCA Bruijnincx, BM Weckhuysen - Angewandte Chemie International …, 2013 - infona.pl
Saying a (bio)mass for the future: The shale gas revolution will strongly impact the availability
of a number of key building blocks of the chemical industry, in particular butadiene and …

CoMo sulfide-catalyzed hydrodeoxygenation of lignin model compounds: An extended reaction network for the conversion of monomeric and dimeric substrates

AL Jongerius, R Jastrzebski, PCA Bruijnincx… - Journal of catalysis, 2012 - Elsevier
In the present work, extensive hydrodeoxygenation (HDO) studies with a commercial sulfided
CoMo/Al 2 O 3 catalyst were performed on a library of lignin model compounds at 50bar …