Electronic tuning of arylnickel (II) complexes by para substitution of the terdentate monoanionic 2, 6-bis [(dimethylamino) methyl] phenyl ligand

LA van de Kuil, H Luitjes, DM Grove, JW Zwikker… - …, 1994 - ACS Publications
Aryl bromides of the type BrCeH2 (CH2NMe2) 2-2, 6-R-4 (R= NH2, MeO, H, Cl, MeC (O))
have been synthesized and have been used to prepare the corresponding organonickel (II) …

Homologous series of liquid-crystalline metal free and copper octa-n-alkoxyphthalocyanines

JF Van der Pol, E Neeleman, JW Zwikker… - Liquid …, 1989 - Taylor & Francis
Two series of discotic liquid crystals, one based on metal-free and the other on copper containing
phthalocyanine (Pc) as the central core and eight peripherally n-alkoxy groups (C 6 –C …

Chirality in polyisocyanides

RJM Nolte, AJM Van Beijnen… - Journal of the American …, 1974 - ACS Publications
If the models are realistic, polyisocyanides consist of racemic mixtures of left-handed and
right-handed helices. In order to prove the occurrence of enan-tiomers, we first tried to …

Synthesis and aggregation behavior of hosts containing phthalocyanine and crown ether subunits

OE Sielcken, MM Van Tilborg, MFM Roks… - Journal of the …, 1987 - ACS Publications
Four new organic hosts are described that contain a phthalocyanine core to which four
crown ether rings are attached. These hosts include a free base phthalocyaninewith 18-crown-6 …

Screw sense selective polymerization of achiral isocyanides catalyzed by optically active nickel (II) complexes

PCJ Kamer, RJM Nolte, W Drenth - Journal of the American …, 1988 - ACS Publications
Results The isocyanides used in this study were synthesized from the corresponding amines
according to the general procedure shown in Scheme I. The amines la-d and If were N-…

Poly (iminomethylenes): rigid rod helical polymers

W Drenth, RJM Nolte - Accounts of Chemical Research, 1979 - ACS Publications
The combination of readily accessible reagents and convenient reactions for the introduction
of selenium, the air stability and ease of manipulation of most organoselenium compounds, …

A 13C‐NMR and IR study of isocyanides and some of their complexes

RW Stephany, MJA De Bie… - Organic Magnetic …, 1974 - Wiley Online Library
13 C chemical shifts and 1 J( 14 N 13 C) coupling constants as well as stretching frequencies
of the isocyano group are reported for some representative aliphatic, unsaturated and …

Mechanistic Aspects of the Kharasch Addition Reaction Catalyzed by Organonickel (II) Complexes Containing the Monoanionic Terdentate Aryldiamine Ligand …

LA van de Kuil, DM Grove, RA Gossage… - …, 1997 - ACS Publications
The addition reaction of polyhalogenated alkanes to alkenes (Kharasch addition reaction) is
homogeneously catalyzed in the absence of O 2 under mild reaction conditions (25 C) by …

A polymer with the mesomorphic order of liquid crystalline phthalocyanines

JF Van der Pol, E Neeleman, JC Van Miltenburg… - …, 1990 - ACS Publications
Phthalocyanines (Pc) substituted with eight terminally functionalized n-alkoxy chains have
been synthesized and their mesomorphic properties investigated. Radical polymerization has …

Discotic liquid crystals Physical parameters of some 2, 3, 7, 8, 12, 13-hexa (alkanoyloxy) truxenes. Observation of a re-entrant isotropic phase in a pure disc-like …

TW Warmerdam, RJM Nolte, W Drenth… - Liquid …, 1988 - Taylor & Francis
The synthesis of a new discotic mesogen, 2,3,7,8,12,13-hexa(octadecanoyloxy)-truxene is
reported. This new compound has been studied using polarization microscopy, differential …