Recent developments in the synthesis of supported catalysts
P Munnik, PE De Jongh, KP De Jong - Chemical reviews, 2015 - ACS Publications
1. INTRODUCTION Heterogeneous catalysis, whereby a gas-or liquid-phase reaction is
performed over a solid catalyst, is at the heart of the modern energy and chemical industries. …
performed over a solid catalyst, is at the heart of the modern energy and chemical industries. …
On the origin of the cobalt particle size effects in Fischer− Tropsch catalysis
JP Den Breejen, PB Radstake… - Journal of the …, 2009 - ACS Publications
The effects of metal particle size in catalysis are of prime scientific and industrial importance
and call for a better understanding. In this paper the origin of the cobalt particle size effects …
and call for a better understanding. In this paper the origin of the cobalt particle size effects …
Confinement of NaAlH4 in Nanoporous Carbon: Impact on H2 Release, Reversibility, and Thermodynamics
J Gao, P Adelhelm, MHW Verkuijlen… - The Journal of …, 2010 - ACS Publications
Metal hydrides are likely candidates for the solid state storage of hydrogen. NaAlH 4 is the
only complex metal hydride identified so far that combines favorable thermodynamics with a …
only complex metal hydride identified so far that combines favorable thermodynamics with a …
Control and impact of the nanoscale distribution of supported cobalt particles used in Fischer–Tropsch catalysis
P Munnik, PE De Jongh… - Journal of the American …, 2014 - ACS Publications
The proximity of nanoparticles may affect the performance, in particular the stability, of
supported metal catalysts. Short interparticle distances often arise during catalyst preparation by …
supported metal catalysts. Short interparticle distances often arise during catalyst preparation by …
Copper nitrate redispersion to arrive at highly active silica-supported copper catalysts
P Munnik, M Wolters, A Gabrielsson… - The Journal of …, 2011 - ACS Publications
In order to obtain copper catalysts with high dispersions at high copper loadings, the gas
flow rate and gas composition was varied during calcination of silica gel impregnated with …
flow rate and gas composition was varied during calcination of silica gel impregnated with …
On the Nature of Oxygen-Containing Surface Groups on Carbon Nanofibers and Their Role for Platinum Deposition An XPS and Titration Study
AJ Plomp, DS Su, KP Jong, JH Bitter - The Journal of Physical …, 2009 - ACS Publications
XPS and acid−base titrations were used to investigate the nature and stability of oxygen-containing
surface groups on carbon nanofibers (CNF) and platinum-containing CNF. During …
surface groups on carbon nanofibers (CNF) and platinum-containing CNF. During …
Support functionalization to retard Ostwald ripening in copper methanol synthesis catalysts
R Van den Berg, TE Parmentier, CF Elkjær… - Acs …, 2015 - ACS Publications
A main reason for catalyst deactivation in supported catalysts for methanol synthesis is
copper particle growth. We have functionalized the support surface in order to suppress the …
copper particle growth. We have functionalized the support surface in order to suppress the …
Quantitative Relationship between Support Porosity and the Stability of Pore-Confined Metal Nanoparticles Studied on CuZnO/SiO2 Methanol Synthesis Catalysts
Metal nanoparticle growth represents a major deactivation mechanism of supported catalysts
and other functional nanomaterials, particularly those based on low melting-point metals. …
and other functional nanomaterials, particularly those based on low melting-point metals. …
Heterogeneities of the nanostructure of platinum/zeolite Y catalysts revealed by electron tomography
J Zecevic, AMJ van der Eerden, H Friedrich… - ACS …, 2013 - ACS Publications
To develop structure–performance relationships for important catalysts, a detailed characterization
of their morphology is essential. Using electron tomography, we determined in three …
of their morphology is essential. Using electron tomography, we determined in three …
Deactivation Behavior of Co/TiO2 Catalysts during Fischer–Tropsch Synthesis
TO Eschemann, KP de Jong - ACS Catalysis, 2015 - ACS Publications
Here we report on the preparation of Co/TiO 2 catalysts (8 and 16 wt % Co) using deposition
precipitation by ammonia evaporation (DPA) and incipient wetness impregnation with …
precipitation by ammonia evaporation (DPA) and incipient wetness impregnation with …