The development of environmental friendly processes in catalysis has been the focus of much
research over the past decade. The attachment of a metal or an organometallic moiety to a …

The coordination chemistry of porphyrins has traditionally involved the ability of the porphyrin's
tetrapyrrolic core to accommodate metal ions of varying charges and sizes, and on the …

Bioinspired copper-model-complexes that react with O 2 provide an opportunity to probe
biological reactivity at a small-molecule level of detail. Biological structural information …

This work reviews recent developments in the field of organic transformations on σ‐aryl
organometallic complexes. The general notion that MC σ bonds are kinetically labile, highly …

Transmetalation of polylithiated, carbosilane (CS) dendrimers functionalized with the
potentially terdentate ligand [C 6 H 2 (CH 2 NMe 2 ) 2 -2,6-R-4] - ( = NCN) with NiCl 2 (PEt 3 ) 2 …

In view of the depletion of petroleum oils, new synthetic routes for the sustainable production
of chemicals, fuels, and energy from renewable biomass sources are currently widely …

The combination of Pd 2 dba 3 ·CHCl 3 and hexacationic triarylphosphine-based Dendriphos
ligands (1−3) leads to a highly active catalytic system in the Suzuki−Miyaura cross-…

An iron complex with a C 1 -symmetric tetradentate N-based ligand catalyzes the asymmetric
epoxidation of cyclic enones and cyclohexene ketones with aqueous hydrogen peroxide, …

On-surface synthesis with molecular precursors has emerged as the de facto route to atomically
well-defined graphene nanoribbons (GNRs) with controlled zigzag and armchair edges. …

Bulky iron complexes are described that catalyze the site‐selective oxidation of alkyl C−H
bonds with hydrogen peroxide under mild conditions. Steric bulk at the iron center is …