Aryl bromides of the type BrCeH2 (CH2NMe2) 2-2, 6-R-4 (R= NH2, MeO, H, Cl, MeC (O))
have been synthesized and have been used to prepare the corresponding organonickel (II) …

The development of environmental friendly processes in catalysis has been the focus of much
research over the past decade. The attachment of a metal or an organometallic moiety to a …

(R'R2NCN')], by reaction with 0.5 equiv of Br2. The molecular structures of three complexes
havebeen determined by X-ray crystallographic methods.[NiBr (C6H3| CH2N (i-Pr) Me| 2-2, 6…

The ester enolate anions are chelate-bonded to the metal center through covalent Zn-0 and
dative Zn-N bonds. The strength of the Zn-N bond, and consequently the thermostability of …

Transmetalation of polylithiated, carbosilane (CS) dendrimers functionalized with the
potentially terdentate ligand [C 6 H 2 (CH 2 NMe 2 ) 2 -2,6-R-4] - ( = NCN) with NiCl 2 (PEt 3 ) 2 …

The reaction of I 2 with platinum “pincer” complexes of the general formula [PtI(NCN‘ ‘)] (NCN‘
‘ = [C 6 H 3 (CH 2 NRR‘) 2 -2,6] - ; R = R‘ = Me or Et; or R = Me, R‘ = t-Bu) is reported. All …

The addition reaction of polyhalogenated alkanes to alkenes (Kharasch addition reaction) is
homogeneously catalyzed in the absence of O 2 under mild reaction conditions (25 C) by …

Asymmetric induction can be achieved in the γ-selective substitution reaction of allylic
substrates (R′CHCHCH 2 Y) with n-BuMgI catalyzed by the chiral arenethiolatocopper(I) …

Aminoarenethiolate−copper(I) complexes are known to be efficient catalysts for carbon−carbon
bond formation. Here, we show the first examples that these thiolate−copper(I) …

The study of catalytically active dendritic materials has become an attractive subject of
intense current interest. 1 Such materials can be obtained either upon attachment of the …